BlueMat team member Professor Franziska Lissel rethinks electronics

A European research team involving Hamburg University of Technology (TUHH) and Deutsches Elektronen-Synchrotron DESY has developed a novel way for converting mechanical energy into electricity – by using water confined in nanometre-sized pores of silicon as the active working fluid.
In a study published in Nano Energy (Elsevier), scientists from CIC energiGUNE (Spain), the University of Ferrara(Italy), the Hamburg University of Technology (TUHH) and DESY(Germany), the University of Silesia in Katowice (Poland), and Riga Technical University (Latvia) — supported by the Cluster of Excellence “BlueMat – Water-Driven Materials” — demonstrate that the cyclic intrusion and extrusion of water in water-repellent nanoporous silicon monoliths can produce measurable electrical power.
Electricity generated by friction in tiny pores
The developed system, known as an Intrusion–Extrusion Triboelectric Nanogenerator (IE-TENG), uses pressure to repeatedly force water into and out of nanoscale pores. During this process, charge generation occurs at the interface between the solid and the liquid. This is a type of friction electricity that often occurs in everyday life. An example that everyone is familiar with: walking across a PVC carpet with shoes on. Electrons transfer from one body to another, accumulating a charge that is suddenly discharged when a third body is touched. For example, when touching a door handle, the charge flows away and you get a small electric shock.
The achieved energy conversion efficiency of up to 9% ranks among the highest ever reported for solid–liquid nanogenerators. “Even pure water, when confined at the nanoscale, can enable energy conversion,” says Prof. Patrick Huber, spokesperson of the BlueMat – Water-Driven Materials Excellence Cluster at the Hamburg University of Technology (TUHH) and DESY. Dr. Luis Bartolomé (CIC energiGUNE) adds: “Combining nanoporous silicon with water enables an efficient, reproducible power source — without exotic materials, but just by using the most abundant semiconductor on earth, silicon, and the most abundant liquid, water.”
Materials design as the key
“A crucial step was the development of precisely engineered silicon structures that are simultaneously conductive, nanoporous, and hydrophobic,” explains Dr. Manuel Brinker from the Hamburg University of Technology. “This architecture allows us to control the motion of water inside the pores — making the energy conversion process both stable and scalable.”The technology paves the way for autonomous, maintenance-free sensor systems — for example in water detection, sports and health monitoring in smart garments, or haptic robotics, where touch or motion directly generates an electrical signal. “Water-driven materials mark the beginning of a new generation of self-sustaining technologies,” emphasize the corresponding authors Prof. Simone Meloni (University of Ferrara) and Dr. Yaroslav Grosu (CIC energiGUNE).
Reference:
 L. Bartolomé et al., Triboelectrification during non-wetting liquids intrusion–extrusion in hydrophobic nanoporous silicon monoliths,
 Nano Energy 146 (2025) 111488.
DOI: 10.1016/j.nanoen.2025.111488

The shiny Christmas tree you see in the image on the right was produced in a porous silica membrane filled with water. Using an infrared laser the photonics team, lead by Prof. Alexander Petrov, locally heat water by several degrees and form vapor bubbles that scatter light creating transparent displays.

Patrick Huber and Stella Gries from Hamburg University of Technology and DESY are investigating how liquids are distributed in thin layers of porous silicon, one of the materials used in BlueMat. They are particularly interested in the capillary forces that cause liquids to rise upwards in small, interconnected tubes, even against gravity. These processes take place so fast that they cannot be detected using standard synchrotron experiments. As silicon is opaque and the pores are highly branched, intense X-rays are needed to analyse it. Together with the team from European XFEL they conducted experiments using MHz X-ray microscopy. The results should help to produce new customised materials, for example for energy storage, e.g. as anode material in batteries, or for new methods of energy harvesting through the repeated wetting and drying of nanoporous materials.

New publication by Patrick Huber's research group in PNAS:
Capillarity-driven flows in nanometer-sized pores play a dominant role in many natural and technological processes, ranging from water transport and transpiration in trees, clay swelling, and catalysis to transport through microfluidic structures and fabrication of battery materials. Here, we show by a combination of experiments and computer simulations of water imbibition in nanopores that the competition between expansive, surface stress release at pore walls and negative, contractile Laplace pressures of nanoscale menisci lead to an unusual macroscopic behavior of the porous medium, which is generic for any liquid/nanoporous solid combination. The results allow one to quantify surface and Laplace stresses and to monitor nanoscale flow and infiltration states by relatively simple length measurements of the porous medium. See also DESY press release.