Prof. Dr. Mikhail Zheludkevich

 

Korrosion und Oberflächentechnik
Institut für Werkstoffforschung, Magnesium Innovation Centre MagIC
Helmholtz-Zentrum Geesthacht

Max-Planck-Str. 1
21502 Geesthacht

 

Tel: +49 4152/87-1988
mikhail.zheludkevich@hzg.de
Website


TOPICS

–  Corrosion protection

–  Coating technology

–  Electrochemistry

EQUIPMENT

– Electrochemical corrosion testing, including impedance spectroscopy (EIS): Computer controlled potentiostats (GIL), "Electrochemical Pen" for measuring of localised corrosion potentials

– Localised electrochemistry: Scanning Vibrating Electrode Technique, Scanning Ion-selective Electrode Technique

– Confocal Raman microscopy: Bruker

– Coating: Plasma electrolytic oxidation (PEO), spin/dip coaters for polymer coatings

– Stress corrosion cracking ("Slow Strain Rate Test"): Tensile test machines: load capacities: 20 to 100 kN, loading rates: 0.1 µm/h to 70 mm/h,  deadweight load frames (20 kN)

– Fatigue testing: Fatigue test machines: load capacities: 10 to 100 kN, loading frequencies: 0.0005 to 200 Hz

– Wear testing: Pin-on-disk wear tester (rotating and oscillating) (load 1 to 60N)

– Accelerated corrosion testing: Salt spray and immersion test cabinets, Natural corrosion test site

– Surface analytical tools: XPS (KRATOS AXIS Ultra DLD),including UV-photo emission (UPS), Auger spectroscopy (SEM/SAM), secondary ion mass spectroscopy (SIMS); temperature range: -100°C to +600°C

– Scanning electron microscopy

– Infrared spectroscopy : BRUKER TENSOR with ATR and grazing incidence

– Infrared microscopy: BRUKER HYPERION 2000 with ATR and grazing incidence

– Grazing incidence angle XRD

CURRENT PROJECTS

PROAIR: Active protection of multi-material assemblies for aircrafts

– MULTISURF - MULTI-functional metallic SURFaces via active Layered Double Hydroxide treatments

– TUMOCS - TUneable Multiferroics based on oxygen OCtahedral Structures

–  SMARCOAT - Development of smart nano and microcapsulated sensing coatings for improving of material durability/performance

– LORCENIS - Long Lasting Reinforced Concrete for Energy Infrastructure under Severe Operating Conditions

RECENT PUBLICATIONS (SCOPUS)

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Abdolah Zadeh, M., Tedim, J., Zheludkevich, M., van der Zwaag, S., Garcia, S.J.: Synergetic active corrosion protection of AA2024-T3 by 2D- anionic and 3D-cationic nanocontainers loaded with Ce and mercaptobenzothiazole. (2018) Corrosion Science, 135, pp. 35-45.

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Hakimizad, A., Raeissi, K., Golozar, M.A., Lu, X., Blawert, C., Zheludkevich, M.L.: Influence of cathodic duty cycle on the properties of tungsten containing Al2O3/TiO2 PEO nano-composite coatings. (2018) Surface and Coatings Technology, 340, pp. 210-221.

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Chen, Y., Lu, X., Blawert, C., Zheludkevich, M.L., Zhang, T., Wang, F.: Formation of self-lubricating PEO coating via in-situ incorporation of PTFE particles. (2018) Surface and Coatings Technology, 337, pp. 379-388.

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Lamaka, S.V., Vaghefinazari, B., Mei, D., Petrauskas, R.P., Höche, D., Zheludkevich, M.L.: Comprehensive screening of Mg corrosion inhibitors. (2017) Corrosion Science, 128, pp. 224-240.

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Ma, X., Blawert, C., Höche, D., Kainer, K.U., Zheludkevich, M.L.: A model describing the growth of a PEO coating on AM50 Mg alloy under constant voltage mode. (2017) Electrochimica Acta, 251, pp. 461-474.

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Hakimizad, A., Raeissi, K., Golozar, M.A., Lu, X., Blawert, C., Zheludkevich, M.L.: The effect of pulse waveforms on surface morphology, composition and corrosion behavior of Al2O3 and Al2O3/TiO2 nano-composite PEO coatings on 7075 aluminum alloy. (2017) Surface and Coatings Technology, 324, pp. 208-221.

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Yang, J., Lu, X., Blawert, C., Di, S., Zheludkevich, M.L.: Microstructure and corrosion behavior of Ca/P coatings prepared on magnesium by plasma electrolytic oxidation. (2017) Surface and Coatings Technology, 319, pp. 359-369.

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Silva, E.L., Höche, D., Bouali, A.C., Serdechnova, M., Sesenes, R.L., Scholz, C.S., Zheludkevich, M.L.: Digital modelling of the galvanic corrosion behaviour of a self–piercing riveted AZ31 - AA5083 hybrid joint [Digitale Modellierung galvanischer Korrosion an stanzgenieteten AZ31-AA5083 Hybridverbunden]. (2017) Materialwissenschaft und Werkstofftechnik, 48 (6), pp. 529-545.

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Mohedano, M., Blawert, C., Yasakau, K.A., Arrabal, R., Matykina, E., Mingo, B., Scharnagl, N., Ferreira, M.G.S., Zheludkevich, M.L.: Characterization and corrosion behavior of binary Mg-Ga alloys. (2017) Materials Characterization, 128, pp. 85-99.

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Kuznetsova, A., Domingues, P.M., Silva, T., Almeida, A., Zheludkevich, M.L., Tedim, J., Ferreira, M.G.S., Cunha, A.: Antimicrobial activity of 2-mercaptobenzothiazole released from environmentally friendly nanostructured layered double hydroxides. (2017) Journal of Applied Microbiology, 122 (5), pp. 1207-1218.

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Mohedano, M., Serdechnova, M., Starykevich, M., Karpushenkov, S., Bouali, A.C., Ferreira, M.G.S., Zheludkevich, M.L.: Active protective PEO coatings on AA2024: Role of voltage on in-situ LDH growth. (2017) Materials and Design, 120, pp. 36-46.

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Mohedano, M., Luthringer, B.J.C., Mingo, B., Feyerabend, F., Arrabal, R., Sanchez-Egido, P.J., Blawert, C., Willumeit-Römer, R., Zheludkevich, M.L., Matykina, E.: Bioactive plasma electrolytic oxidation coatings on Mg-Ca alloy to control degradation behaviour. (2017) Surface and Coatings Technology, 315, pp. 454-467.

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Klein, M., Lu, X., Blawert, C., Kainer, K.U., Zheludkevich, M.L., Walther, F.: Influence of plasma electrolytic oxidation coatings on fatigue performance of AZ31 Mg alloy. (2017) Materials and Corrosion, 68 (1), pp. 50-57.

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Lu, X., Schieda, M., Blawert, C., Kainer, K.U., Zheludkevich, M.L.: Formation of photocatalytic plasma electrolytic oxidation coatings on magnesium alloy by incorporation of TiO2 particles. (2016) Surface and Coatings Technology, 307, pp. 287-291.

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Lu, X., Mohedano, M., Blawert, C., Matykina, E., Arrabal, R., Kainer, K.U., Zheludkevich, M.L.: Plasma electrolytic oxidation coatings with particle additions – A review. (2016) Surface and Coatings Technology, 307, pp. 1165-1182.

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Yasakau, K.A., Giner, I., Vree, C., Ozcan, O., Grothe, R., Oliveira, A., Grundmeier, G., Ferreira, M.G.S., Zheludkevich, M.L.: Influence of stripping and cooling atmospheres on surface properties and corrosion of zinc galvanizing coatings. (2016) Applied Surface Science, 389, pp. 144-156.

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Yasakau, K.A., Kallip, S., Lisenkov, A., Ferreira, M.G.S., Zheludkevich, M.L.: Initial stages of localized corrosion at cut-edges of adhesively bonded Zn and Zn-Al-Mg galvanized steel. (2016) Electrochimica Acta, 211, pp. 126-141.

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Tedim, J., Bastos, A.C., Kallip, S., Zheludkevich, M.L., Ferreira, M.G.S.: Corrosion protection of AA2024-T3 by LDH conversion films. Analysis of SVET results. (2016) Electrochimica Acta, 210, pp. 215-224.

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Mohedano, M., Matykina, E., Arrabal, R., Mingo, B., Zheludkevich, M.L.: PEO of rheocast A356 Al alloy: energy efficiency and corrosion properties. (2016) Surface and Interface Analysis, 48 (8), pp. 953-959.

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Rico-Oller, B., Mertens, T., Kolb, M., Wehr, J., Zheludkevich, M.: Environmentally friendly anodising process for structural bonding of titanium. (2016) Materialwissenschaft und Werkstofftechnik, 47 (5-6), pp. 400-408.

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Zheludkevich, M.L., Hughes, A.E.: Delivery systems for self healing protective coatings. (2016) Springer Series in Materials Science, 233, pp. 157-199.

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Hughes, A.E., Mol, J.M.C., Zheludkevich, M.L., Buchheit, R.G.: Introduction. (2016) Springer Series in Materials Science, 233, pp. 1-17.

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Lu, X., Blawert, C., Kainer, K.U., Zheludkevich, M.L.: Investigation of the formation mechanisms of plasma electrolytic oxidation coatings on Mg alloy AM50 using particles. (2016) Electrochimica Acta, 196, pp. 680-691.

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Lu, X., Blawert, C., Mohedano, M., Scharnagl, N., Zheludkevich, M.L., Kainer, K.U.: Influence of electrical parameters on particle uptake during plasma electrolytic oxidation processing of AM50 Mg alloy. (2016) Surface and Coatings Technology, 289, pp. 179-185.

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Galvão, T.L.P., Kuznetsova, A., Gomes, J.R.B., Zheludkevich, M.L., Tedim, J., Ferreira, M.G.S.: A computational UV–Vis spectroscopic study of the chemical speciation of 2-mercaptobenzothiazole corrosion inhibitor in aqueous solution. (2016) Theoretical Chemistry Accounts, 135 (3), art. no. 78.

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Zheludkevich, M.L., Kallip, S., Serdechnova, M.: Protection of multimaterial assemblies. (2016) Nanomaterials in Joining, pp. 73-102.

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Lamaka, S.V., Höche, D., Petrauskas, R.P., Blawert, C., Zheludkevich, M.L.: A new concept for corrosion inhibition of magnesium: Suppression of iron re-deposition. (2016) Electrochemistry Communications, 62, pp. 5-8.

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Klein, M., Lu, X., Blawert, C., Kainer, K.U., Zheludkevich, M.L., Walther, F.: Influence of plasma electrolytic oxidation coatings on fatigue performance of AZ31 Mg alloy. (2016) Materials and Corrosion. Article in Press.

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Lu, X., Blawert, C., Huang, Y., Ovri, H., Zheludkevich, M.L., Kainer, K.U.: Plasma electrolytic oxidation coatings on Mg alloy with addition of SiO2 particles. (2016) Electrochimica Acta, 187, pp. 20-33.

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Serdechnova, M., Salak, A.N., Barbosa, F.S., Vieira, D.E.L., Tedim, J., Zheludkevich, M.L., Ferreira, M.G.S.: Interlayer intercalation and arrangement of 2-mercaptobenzothiazolate and 1,2,3-benzotriazolate anions in layered double hydroxides: In situ X-ray diffraction study. (2016) Journal of Solid State Chemistry, 233, pp. 158-165.

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Maia, F., Yasakau, K.A., Carneiro, J., Kallip, S., Tedim, J., Henriques, T., Cabral, A., Venâncio, J., Zheludkevich, M.L., Ferreira, M.G.S.: Corrosion protection of AA2024 by sol-gel coatings modified with MBT-loaded polyurea microcapsules. (2016) Chemical Engineering Journal, 283, pp. 1108-1117.

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Kuznetsov, B., Serdechnova, M., Tedim, J., Starykevich, M., Kallip, S., Oliveira, M.P., Hack, T., Nixon, S., Ferreira, M.G.S., Zheludkevich, M.L.: Sealing of tartaric sulfuric (TSA) anodized AA2024 with nanostructured LDH layers. (2016) RSC Advances, 6 (17), pp. 13942-13952.

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Ivanou, D.K., Yasakau, K.A., Kallip, S., Lisenkov, A.D., Starykevich, M., Lamaka, S.V., Ferreira, M.G.S., Zheludkevich, M.L.: Active corrosion protection coating for a ZE41 magnesium alloy created by combining PEO and sol-gel techniques. (2016) RSC Advances, 6 (15), pp. 12553-12560.

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Mohedano, M., Blawert, C., Zheludkevich, M.L.: Silicate-based Plasma Electrolytic Oxidation (PEO) coatings with incorporated CeO2 particles on AM50 magnesium alloy. (2015) Materials and Design, 86, pp. 735-744.

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Höche, D., Blawert, C., Lamaka, S.V., Scharnagl, N., Mendis, C., Zheludkevich, M.L.: The effect of iron re-deposition on the corrosion of impurity-containing magnesium. (2015) Physical Chemistry Chemical Physics, 18 (2), pp. 1279-1291.

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Ma, X., Blawert, C., Höche, D., Zheludkevich, M.L., Kainer, K.U.: Investigation of electrode distance impact on PEO coating formation assisted by simulation. (2015) Applied Surface Science, . Article in Press.

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Starykevich, M., Salak, A.N., Ivanou, D.K., Lisenkov, A.D., Zheludkevich, M.L., Ferreira, M.G.S.: Electrochemical deposition of zinc from deep eutectic solvent on barrier alumina layers. (2015) Electrochimica Acta, 170, pp. 284-291.

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Silva, E.L., Gouvêa, C.P., Quevedo, M.C., Neto, M.A., Archanjo, B.S., Fernandes, A.J.S., Achete, C.A., Silva, R.F., Zheludkevich, M.L., Oliveira, F.J.: All-Diamond Microelectrodes as Solid State Probes for Localized Electrochemical Sensing. (2015) Analytical Chemistry, 87 (13), pp. 6487-6492.

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Maia, F., Silva, A.P., Fernandes, S., Cunha, A., Almeida, A., Tedim, J., Zheludkevich, M.L., Ferreira, M.G.S.: Incorporation of biocides in nanocapsules for protective coatings used in maritime applications. (2015) Chemical Engineering Journal, 270, pp. 150-157.

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Salak, A.N., Ignatenko, O.V., Zhaludkevich, A.L., Lisenkov, A.D., Starykevich, M., Zheludkevich, M.L., Ferreira, M.G.S.: High-pressure zinc oxysulphide phases in the ZnO-ZnS system. (2015) Physica Status Solidi (A) Applications and Materials Science, 212 (4), pp. 791-795.

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Oliveira, A.B., Bastos, A.C., Fernandes, C.M., Pinho, C.M.S., Senos, A.M.R., Soares, E., Sacramento, J., Zheludkevich, M.L., Ferreira, M.G.S.: Corrosion behaviour of WC-10% AISI 304 cemented carbides. (2015) Corrosion Science, . Article in Press.

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Mohedano, M., Blawert, C., Zheludkevich, M.L.: Cerium-based sealing of PEO coated AM50 magnesium alloy. (2015) Surface and Coatings Technology, 269 (1), pp. 145-154.

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Kalanda, N.A., Kovalev, L.V., Waerenborgh, J.C., Soares, M.R., Zheludkevich, M.L., Yarmolich, M.V., Sobolev, N.A.: Interplay of superstructural ordering and magnetic properties of the Sr2FeMoO6-δ double perovskite. (2015) Science of Advanced Materials, 7 (3), pp. 446-454.

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Muhaffel, F., Mert, F., Cimenoglu, H., Höche, D., Zheludkevich, M.L., Blawert, C.: Characterisation and corrosion behaviour of plasma electrolytic oxidation coatings on high pressure die cast Mg-5Al-0.4Mn-xCe (x=0, 0.5, 1) alloys. (2015) Surface and Coatings Technology, 269 (1), pp. 200-211.

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Lu, X., Sah, S.P., Scharnagl, N., Störmer, M., Starykevich, M., Mohedano, M., Blawert, C., Zheludkevich, M., Kainer, K.U.: Degradation behavior of PEO coating on AM50 magnesium alloy produced from electrolytes with clay particle addition. (2015) Surface and Coatings Technology, 269 (1), pp. 155-169.

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Salak, A.N., Ignatenko, O.V., Zhaludkevich, A.L., Lisenkov, A.D., Starykevich, M., Zheludkevich, M.L., Ferreira, M.G.S.: High-pressure zinc oxysulphide phases in the ZnO-ZnS system. (2015) Physica Status Solidi (A) Applications and Materials Science, . Article in Press.

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Carneiro, J., Caetano, A.F., Kuznetsova, A., Maia, F., Salak, A.N., Tedim, J., Scharnagl, N., Zheludkevich, M.L., Ferreira, M.G.S.: Polyelectrolyte-modified layered double hydroxide nanocontainers as vehicles for combined inhibitors. (2015) RSC Advances, 5 (50), pp. 39916-39929.